Synthesis of SiC Fine Particles by Gas-Phase Reaction Under Short-Time Microgravity

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Okutani,T./ Nakata,Y./ Suzuki,M./ Maniette,Y./ Goto,N./ Odawara,O./ Mori,K.
1995”N3ŒŽ –kŠC“¹H‹Æ‹ZpŒ¤‹†Š•ñ 64,44-49

@SiC fine particles were synthesized by the gas-phase thermal decomposition of tetramethylsilane (Si(CH3)4) in hydrogen under microgravity of 10-4G for 10 sec. Rapid heating to the temperature over 800Ž which is required for thermal decomposition of Si(CH3)4 under short-time microgravity was attained using a chemical oven where the heat of exothermic reaction of combustion synthesis of Ti-Al-4B composites was used as the heat source. Monodisperse and spherical SiC fine particles were synthesized under microgravity, whereas aggregates of SiC fine particles were synthesized under 1 G gravity. The SiC particles synthesized under microgravity(150-200 nm) were bigger in size and narrower in size distribution than those under 1 G gravity(100-150 nm).