P204
Synthesis and Properties of Novel Ru-Ni and Ru-Cu Dinuclear Complexes
N. Komatsuzaki, Y. Himeda, M. Goto, K. Kasuga, H. Sugihara, H. Arakawa
NIMC
Novel Ru-Ni and Ru-Cu dinuclear complexes, in which Ru(bpy)22+ (bpy = 2,2-bipyridine) and Ni- or Cu-Schiff base unit fused together, were synthesized. The molecular structure of Ru-Ni dinuclear complex was determined by an X-ray crystal structure analysis. Photochemical studies on these complexes showed that the excited state of the Ru(bpy)22+ moiety in the dinuclear complexes was quenched by intramolecularly attached metal-Schiff base unit.
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