P103
Laser spectroscopy of silver-ammonia complexes
Jun Miyawaki, Ko-ichi Sugawara, and Harutoshi Takeo
NIMC, NAIR
The electronic spectra of the silver-ammonia complexes have been observed. The complexes were formed using laser ablation and cooled in a free jet expansion, and their spectra were observed through resonantly enhanced multiphoton ionization (REMPI) method. The origines of these band systems are largely red-shifted from the corresponding transition of silver atom, indicationg a significant stabilization upon electronic excitaion.
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