L201
Synthesis and properties of novel photoactive polynuclear metal complexes
K. Kasuga
NIMC
Polynuclear transiton metal complexes have attracted much attention in terms of effective intramolecular elctron and/or energy transfer systems.
Especially polynulear complexes incorporating rutheniumu (Ru) polypyridine complex have been studied extensively because of its attractive photochemical properties.
We synthesized several novel types of hetero- or homo-binucler complexes having Ru(bpy)2+ moiety.
In these complexes, bisphenthroline and 5,6-diaminophenathroline derivaties were used as bridging ligands.
Photo- and electro-chemical properties of these complexes were also investigated.
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